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Sam and Cat meet when a wild dilemma lands them in the back of a moving garbage truck. After becoming friends, they babysit three kids, which give them the idea to start their own babysitting service.
Sam and Cat babysit a boy who asks a lot of questions, and one who can't stop hugging. Sam finds a special way to save their favourite TV show about a family of cross-dressers from being cancelled.
Sam and Cat babysit two proper and polite British girls who turn out to be con artists. Sam goes to Elderly Acres in an attempt to fulfill a community service requirement for her online high school.
Sam and Cat babysit a Pygmy goat while trying to win over Dilben, their landlord's obnoxious son, who is trying to get the girls evicted. Dice begins managing Goomer, a huge but dim-witted MMA fighter.
Cat discovers Sam is really fast at texting and convinces her to compete in a texting competition against a sweet boy who has an overbearing mom. Dice tries to avoid an annoying old friend.
When a babysitting client says, "You're my favourite babysitter ever", Sam and Cat debate which one of them he meant and vie for their new clients' affection to see who really is the best babysitter.
When Sam and Cat agree to babysit Goomer while Dice goes away, they misapply Goomer's medication which causes him to temporarily lose his eyesight before a big match.
A competing babysitting service is posting fake, bad reviews about Sam and Cat's babysitting service. The girls confront their new competition and discover they're not what they appear to be.